Intercalation Chemistry

Intercalation Chemistry PDF Book Detail:
Author: Stanley M Whittingha
Publisher: Elsevier
ISBN: 0323140408
Size: 63.63 MB
Format: PDF, ePub
Category : Science
Languages : en
Pages : 611
View: 1058

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Book Description: Intercalation Chemistry introduces the specialist reader to the breadth of intercalation chemistry and the newcomer to the diverse research opportunities and challenges available in synthetic and reaction chemistry and also in the controlled modification of physical properties. Topics covered range from graphite chemistry to sheet silicate intercalates, diffusion and shape-selective catalysis in zeolites, organic and organometallic intercalation compounds of the transition metal dichalcogenides, and solvated intercalation compounds of layered chalcogenide and oxide bronzes. This book is comprised of 18 chapters and begins with an introduction to intercalation chemistry. The discussions that follow focus on the intercalation chemistry of graphite and of complex oxides with both two (clays and acid phosphates)- and three (zeolites)-dimensional structures, along with organic conversions that have been discovered using essentially smectite (i.e., montmorillonite- and hectorite-based) intercalates. The next chapters focus on ß-aluminas, acid salts of tetravalent metals with layered structure, and layered chalcogenides and halides with simple and hydrated cations as well as organic and organometallic ions. The book also considers the chemistry, thermodynamics, and applications of intermetallic compounds that incorporate hydrogen, intercalation in the context of biological systems, crystallographic shear structures, and intercalation reactions of oxides and chalcogenides of vanadium, molybdenum, and tungsten. The final chapter touches on the physical properties of some intercalation compounds of the dichalcogenides. This book is intended for researchers in the various materials science disciplines.

Intercalation Chemistry And Charge Storage In Solution Processed Layered Mopo4 M

Intercalation Chemistry and Charge Storage in Solution processed Layered MOPO4  M PDF Book Detail:
Author: Yue Zhu (Ph. D.)
Publisher:
ISBN:
Size: 13.27 MB
Format: PDF
Category :
Languages : en
Pages : 246
View: 7056

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Book Description: Intercalation chemistry, despite being an old field with more than a century of history, has recently gained renewed interest owing to the rise of two-dimensional (2D) nanomaterials and their associated scientific and technological importance. The relevance of intercalation chemistry to this family of materials includes liquid exfoliation of layered materials, tuning their physical and chemical properties by intercalation, charge storage in thin 2D nanosheets, electrochemical intercalation in 2D heterostructures, etc. Some are old topics demanding fresh understanding in new material systems, and some are unprecedented ideas that will be exciting to explore. This dissertation examines intercalation chemistry and charge storage in layered MOPO4 (M=V, Nb) hydrates, which is an interesting material system that differs in several unique ways from many previously studied intercalation hosts. This system is also less popular in literature compared with classic ones, such as graphite and transition metal dichalcogenides, but is more structurally complicated and offers more research opportunities. Historically, some aspects of the intercalation product and kinetics regarding the use of a bulky metallocene as intercalation guest remain elusive, and the charge storage mechanism of small alkali-ions in the presence of interlayer water has not been well understood. This work presents research efforts to answer such open questions in these materials through a combined experimental and theoretical approach. Following a brief overview of intercalation chemistry and its most up to date development (Chapter 1), materials synthesis involving solution processing methods to obtain microcrystals and nanosheets of MOPO4 hydrates is described (Chapter 2). The subsequent in-depth studies are divided into two major parts using either microcrystals or nanosheets as intercalation host. The first part discusses the intercalation of ferrocene into microcrystals of VOPO4·2H2O in terms of resolving intercalated structures and understanding solvent-dependent kinetics (Chapter 3). The second part details the charge storage in nanosheets of MOPO4 with implications on Li- and Na-ion battery applications (Chapter 4). Finally, key contributions to the intercalation chemistry of the title material system are summarized and possible future directions are provided (Chapter 5)

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Size: 67.32 MB
Format: PDF
Category : Aeronautics
Languages : en
Pages :
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Reviews In Inorganic Chemistry

Reviews in Inorganic Chemistry PDF Book Detail:
Author:
Publisher:
ISBN:
Size: 70.71 MB
Format: PDF, ePub
Category : Chemistry, Inorganic
Languages : en
Pages :
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